Stannane, chlorotris(2-methyl-2-phenylpropyl)- → Tris(beta,beta-dimethylphenethyl)tin caprylate

HRID 256383

반응식

HRID 256383 반응식
[C:1]([O-:10])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[Na+].[CH3:12][C:13]([CH3:43])([C:37]1[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1)[CH2:14][Sn:15](Cl)([CH2:26][C:27]([CH3:35])([CH3:34])[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)[CH2:16][C:17]([CH3:25])([CH3:24])[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1>C(O)(C)C>[C:1]([O-:10])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH3:24][C:17]([CH3:25])([C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1)[CH2:16][Sn+:15]([CH2:26][C:27]([CH3:34])([CH3:35])[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)[CH2:14][C:13]([CH3:12])([CH3:43])[C:37]1[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1

참가 물질

4

반응물 2

HCID 70898Stannane, chlorotris(2-methyl-2-phenylpropyl)-HCID 23664772Sodium octanoate

생성물 1

HCID 20163799Tris(beta,beta-dimethylphenethyl)tin caprylate수율 94.8%

시약·촉매·용매 1

HCID 3776Isopropanol용매

반응 조건

온도
50 °C

실험 절차

Sodium caprylate 6.6 g was added to 200 ml of isopropanol, and with stirring, the mixture was heated to 50° C. To the resulting solution was added 22.2 g of tris(β,β-dimethylphenethyl)tin chloride over 30 minutes. The mixture was further stirred for 30 minutes. The insoluble material precipitated was separated by filtration, and the filtrate was concentrated to give 25.1% (yield 94.8%) of tris(β,β-dimethylphenethyl)tin caprylate as a slightly pale yellow viscous syrup.

후처리

  1. stirringThe mixture was further stirred for 30 minutes
  2. customThe insoluble material precipitated
  3. customwas separated by filtration
  4. concentrationthe filtrate was concentrated

출처 및 근거

ORD 기록
ord-f8127e71572a42c085d969477bdc91a0
출처 데이터셋
uspto-grants-1987_10
특허 번호
US04703059

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