2,3,4,5-Tetramethylpyridine → Phthalocyanine

HRID 256510

반응식

HRID 256510 반응식
[Li].[CH:2]1[CH:3]=[CH:4][C:5]2[C:6](=[C:8]3[N:40]=[C:39]4[N:41]=[C:32]([C:33]5[CH:34]=[CH:35][CH:36]=[CH:37][C:38]=54)[N:31]=[C:29]4[NH:30][C:22]([C:23]5[CH:24]=[CH:25][CH:26]=[CH:27][C:28]=54)=[N:21][C:19]4=[N:20][C:12]([C:13]5[CH:14]=[CH:15][CH:16]=[CH:17][C:18]=54)=[N:11][C:10]=2[NH:9]3)[CH:7]=1.CC1C(C)=C(C)C(C)=NC=1>>[CH:3]1[CH:2]=[CH:7][C:6]2[C:5](=[C:10]3[N:11]=[C:12]4[N:20]=[C:19]([C:18]5[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=54)[N:21]=[C:22]4[NH:30][C:29]([C:28]5[CH:27]=[CH:26][CH:25]=[CH:24][C:23]=54)=[N:31][C:32]4=[N:41][C:39]([C:38]5[CH:37]=[CH:36][CH:35]=[CH:34][C:33]=54)=[N:40][C:8]=2[NH:9]3)[CH:4]=1

참가 물질

3

반응물 2

HCID 876442,3,4,5-TetramethylpyridineHCID 136122626CID 136122626

생성물 1

HCID 86280045Phthalocyanine

실험 절차

For this preparation, dilithiated lithium phthalocyanine is contacted with (2H)-2,2,6,6-tetramethylpiperidine. The latter was prepared by H-D isotopic exchange between commercially available tetramethylpyridine (TMP) and 2H2O at ambient temperature, followed by a separation of the organic phase and the aqueous phase by ether addition.

후처리

  1. customfollowed by a separation of the organic phase
  2. additionthe aqueous phase by ether addition

출처 및 근거

ORD 기록
ord-0172df0db5aa4bbc92d75b5aa16205b4
출처 데이터셋
uspto-grants-1993_11
특허 번호
US05258313

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