Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dimethyldioxirane → N-(1-Hydroxy-2,6-diphenyl-3,5-dimethylpiperidin-4-yl)lauramide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dimethyldioxirane | HCID 115197 | — |
| 반응물 | N-(2,6-Diphenyl-3,5-dimethylpiperidin-4-yl)lauramide | HCID 18954068 | — |
| 용매 | Acetone | HCID 180 | — |
| 생성물 | N-(1-Hydroxy-2,6-diphenyl-3,5-dimethylpiperidin-4-yl)lauramide | HCID 18954070 | — |
반응 단계
Following the general procedure of Example 2 and using 8.56 g (18.5 mmol) of N-(2,6-diphenyl-3,5-dimethylpiperidin-4-yl)lauramide, prepared in Example 11, and 462 ml of a 0.04 molar solution of dimethyldioxirane (18.5 mmol) in acetone, the title compound is isolated in a yield of 7.37 g (70%) after purification by LC (silica gel; ethyl acetate:hexanes) as a white solid melting at 58°-62° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05262538 |
| 출처 데이터셋 | uspto-grants-1993_11 |
| ORD ID | ord-f164c3033b6f4fd29e3a3ffdd6d970c8 |
| 출처 메모 | uspto-grants-1993_11 |