Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2,4'-Dichloroacetophenone → 4-Chloro-alpha-(chloromethyl)benzenemethanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2,4'-Dichloroacetophenone | HCID 70298 | — |
| 반응물 | Ethanone, 2-chloro-1-(3-chlorophenyl)- | HCID 168006 | — |
| 반응물 | 2-Bromo-2'-chloroacetophenone | HCID 2735785 | — |
| 생성물 | 4-Chloro-alpha-(chloromethyl)benzenemethanol | HCID 110834 | — |
| 생성물 | 2-Chloro-1-(3-chloro-phenyl)-ethanol | HCID 11469563 | — |
| 생성물 | 2-Chloro-1-(2-chlorophenyl)ethanol | HCID 13634268 | — |
반응 단계
Bio-reaction and analysis were carried out in the same way as described in Example 2 except that as substrate was used 3.25 g each of 2-bromo-1-(2'-chlorophenyl) ethanone, 2-chloro-1-(3'-chlorophenyl) ethanone and 2-chloro-1-(4'-chlorophenyl) ethanone instead of 2-bromo-1-(3'-chlorophenyl) ethanone and as the reaction products (-)-2-chloro-1-(2'-chlorophenyl) ethanol, (-)-2-chloro-1-(3'-chlorophenyl) ethanol and (-)-2-chloro-1-(4'-chlorophenyl) ethanol were obtained respectively. The yields and physical properties of the respective reaction products were as shown in Table 4.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05266485 |
| 출처 데이터셋 | uspto-grants-1993_11 |
| ORD ID | ord-c8e1392a69634f7f926aace508c7f625 |
| 출처 메모 | uspto-grants-1993_11 |