참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Hydrochloric Acid | HCID 313 | — |
| 반응물 | Diethyl Carbonate | HCID 7766 | — |
| 반응물 | 1-Bromodecane | HCID 8173 | — |
| 반응물 | Magnesium | HCID 5462224 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | Tri-n-decylcarbinol | HCID 19690419 | — |
반응 단계
Three moles of 1-bromodecane was slowly added to 3 moles of magnesium turnings in 0.6 liters of anhydrous ethyl ether (nitrogen atmosphere). One mole of diethyl carbonate in 0.151 anhydrous ethyl ether was slowly added to the mixture. After stirring for one hour at 30° C., the mixture was slowly poured into 1.8 liters of a cold 10% HCl solution. The organic layer was dried with magnesium sulfate and the ethyl ether evaporated off to give tri-n-decylcarbinol.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05728907 |
|---|
| 출처 데이터셋 | uspto-grants-1998_03 |
|---|
| ORD ID | ord-5831ca84c85c45188e821732a2150987 |
|---|
| 출처 메모 | uspto-grants-1998_03 |
|---|
