Cyanuric chloride → Anthraquinone

HRID 258358

반응식

HRID 258358 반응식
N[C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5](SC2C=CC(S(O)(=O)=O)=C(N)C=2)=[CH:4][C:3]=1Br.N1C(Cl)=NC(Cl)=NC=1Cl.NC1C=C(S(O)(=O)=O)C=CC=1>>[CH:9]1[C:8]2[C:7](=[O:17])[C:6]3[C:15](=[CH:2][CH:3]=[CH:4][CH:5]=3)[C:14](=[O:16])[C:13]=2[CH:12]=[CH:11][CH:10]=1

참가 물질

4

반응물 3

HCID 7954Cyanuric chlorideHCID 84743-Aminobenzenesulfonic acidHCID 197377001-Amino-2-bromo-4-(3'-amino-4'-sulfophenylthio)anthraquinone

생성물 1

HCID 6780Anthraquinone

실험 절차

1-Amino-2-bromo-4-(3'-amino-4'-sulfophenylthio)anthraquinone (10.1 parts), cyanuric chloride (3.7 parts) and 1-aminobenzene-4-β-sulfatoethylsulfone (5.6 parts) were subjected to condensation reactions one after another in an aqueous medium in a usual manner, followed by a condensation reaction with 3-aminobenzenesulfonic acid (3.5 parts) at 50° to 70° C. under a weak acid condition. Thereafter, salting out of the reaction mixture gave an anthraquinone compound of the following formula (free acid form). ##STR322##

출처 및 근거

ORD 기록
ord-18d078d7c7ec46f5876ce6d7f1333931
출처 데이터셋
uspto-grants-1993_11
특허 번호
US05266696

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