Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
I2-Ionone → Retinal
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | I2-Ionone | HCID 638014 | — |
| 반응물 | Potassium tert-butoxide | HCID 23665647 | — |
| 반응물 | HCID 86747400 | HCID 86747400 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | Retinal | HCID 638015 | — |
반응 단계
Phosphonate (I) (0.5 g, 1.72 mmol) in solution in THF (10 ml) was introduced under argon into a 25-ml two-necked flask. Potassium tert-butylate (0.275 g, 2.22 mmol) was added in small portions at -70° C. Stirring was continued at -70° C. for 90 minutes. β-ionone (0.34 g, 1.8 mmol) in solution in THF (1 ml) was then added. The solution was kept at -70° C. for 15 minutes and then at -20° C. for 1 hour.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05266708 |
| 출처 데이터셋 | uspto-grants-1993_11 |
| ORD ID | ord-d6fb2adbd05e4aa6a024f9565b371433 |
| 출처 메모 | uspto-grants-1993_11 |