Ammonium → Cerium acetylacetone-monohydrate

반응식

[C:1]([CH2:4][C:5](=[O:7])[CH3:6])(=[O:3])[CH3:2].O.[NH4+].[N+]([O-])([O-])=O.[Ce+3:14].[N+]([O-])([O-])=O.[N+]([O-])([O-])=O>>[OH2:3].[C:1]([CH2:4][C:5](=[O:7])[CH3:6])(=[O:3])[CH3:2].[Ce:14]

참가 물질

반응물 4

HCID 223Ammonium

HCID 962Water

HCID 24948Cerium nitrate

HCID 31261Acetylacetone

생성물 1

HCID 86734909Cerium acetylacetone-monohydrate

실험 절차

In an Erlenmeyer flask of 1 liter capacity, 6.51 grams of cerium nitrate and 4.5 grams of acetylacetone are dissolved in 300 ml. of distilled water. A 2% ammonium solution is added in drops, shaking vigorously, until a pH value of exactly 8.0 is achieved. This results in a light yellow precipitate of cerium acetylacetone-monohydrate, identified by the formula Ce(CH3COCHCOCH3)3. H2 0 which is suctioned off by a Buechner funnel and rinsed with 300 ml. of distilled water. The precipitate is dried under high vacuum without heating until a dust-like or pulverulent product is obtained.