참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Hydrochloric Acid | HCID 313 | — |
| 반응물 | Diethyl Carbonate | HCID 7766 | — |
| 반응물 | 1-Bromooctane | HCID 8140 | — |
| 반응물 | Magnesium | HCID 5462224 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | 9-Octylheptadecan-9-ol | HCID 87239 | — |
반응 단계
This compound may be prepared in the following manner. Three moles of n-octylbromide are slowly added to 3 moles of magnesium turnings in 0.6 liters of anhydrous ethyl ether (nitrogen atmosphere). One mole of diethyl carbonate in 0.151 anhydrous ethyl ether is slowly added to the mixture. The mixture is stirred for one hour at 30° C., then the mixture is slowly poured into 1.8 liters of a cold 10% HCl solution. The organic layer is dried with magnesium sulfate and the ethyl ether is evaporated off to give tri-n-octylcarbinol.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05728907 |
|---|
| 출처 데이터셋 | uspto-grants-1998_03 |
|---|
| ORD ID | ord-53f58a0bd1b3472b91143912053c2870 |
|---|
| 출처 메모 | uspto-grants-1998_03 |
|---|
