Ethanol → HCID 131710840, 화합물

HRID 258795노트

반응식

HRID 258795 반응식
[CH2:1]([NH:3][C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH3:10])[CH:5]=1)[CH3:2].CCO[CH2:14][CH2:15][O:16][CH2:17][CH2:18]Br.C(=O)(O)[O-].[Na+].[CH2:25]([OH:27])[CH3:26]>O>[CH2:1]([N:3]([CH2:26][CH2:25][O:27][CH:17]([O:16][CH2:15][CH3:14])[CH3:18])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH3:10])[CH:5]=1)[CH3:2]

참가 물질

6

반응물 4

HCID 702EthanolHCID 7603N-ethyl-3-methylanilineHCID 516892Sodium BicarbonateHCID 70153241-Bromo-2-(2-ethoxyethoxy)ethane

생성물 1

HCID 131710840HCID 131710840, 화합물

시약·촉매·용매 1

HCID 962Water용매

실험 절차

A mixture of 67.5 g(0.5 mole) of N-ethyl-3-methyl-aniline, 98.5 g (0.5 mole) of [β-(β-ethoxy)-ethoxy]ethyl bromide, 44.1 g (0.55 mole) of sodium bicarbonate, 5.50 ml of ethanol and 145 ml of water was refluxed for 80 hours. Ethanol was removed by distillation and the oil layer was extracted with ether. The extract was dried with potassium carbonate and then ether was removed, followed by distillation of the residue oil under reduced pressure.

후처리

  1. temperaturewas refluxed for 80 hours
  2. customEthanol was removed by distillation
  3. extractionthe oil layer was extracted with ether
  4. dry with materialThe extract was dried with potassium carbonate
  5. customether was removed
  6. distillationfollowed by distillation of the residue oil under reduced pressure

출처 및 근거

ORD 기록
ord-a3059631fdba4057814c471ea83120ab
출처 데이터셋
uspto-grants-1977_07
특허 번호
US04035188

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