반응식
C[O:2][C:3]([C:5]1[CH:10]=[CH:9][C:8]([S:11]([CH2:13][C:14]2[CH:19]=[CH:18][CH:17]=[C:16]([Cl:20])[CH:15]=2)=[O:12])=[CH:7][N:6]=1)=[O:4].CO.[OH-].[Na+:24]>>[Cl:20][C:16]1[CH:15]=[C:14]([CH:19]=[CH:18][CH:17]=1)[CH2:13][S:11]([C:8]1[CH:9]=[CH:10][C:5]([C:3]([O-:4])=[O:2])=[N:6][CH:7]=1)=[O:12].[Na+:24]참가 물질
3
실험 절차
To the stirred mixture of 9 g of 5-(m-chlorobenzylsulfinyl)-2-pyridinecarboxylic acid methyl ester and 40 ml of N aqueous sodium hydroxide methanol is added until dissolution occurs. The solution is heated at the steam bath for 10 minutes and stirred overnight at room temperature. It is evaporated, the residue taken up in the minimum amount of hot water, the solution filtered, the filtrate cooled and the precipitate formed collected, to yield the sodium 5-(m-chlorobenzylsulfinyl)-2-pyridinecarboxylate.
후처리
- additionis added until dissolution
- temperatureThe solution is heated at the steam bath for 10 minutes
- customIt is evaporated
- filtrationthe solution filtered
- temperaturethe filtrate cooled
- customthe precipitate formed
- customcollected
출처 및 근거
- ORD 기록
- ord-8193c3a539c04da494a76533be71fa8b
- 출처 데이터셋
- uspto-grants-1977_07
- 특허 번호
- US04036965
연결된 노트
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