Butyric Acid → Heptafluorobutyric acid

반응식

[F:1][C:2]([F:13])([C:9]([F:12])([F:11])[F:10])[C:3]([F:8])([F:7])[C:4]([F:6])=[O:5].C(O)(=[O:18])CCC.C(OC(=O)CCC)(=O)CCC>>[F:10][C:9]([F:12])([F:11])[C:2]([F:13])([F:1])[C:3]([F:8])([F:7])[C:4]([OH:18])=[O:5].[C:4]([F:6])(=[O:5])[CH2:3][CH2:2][CH3:9]

참가 물질

반응물 3

HCID 264Butyric Acid

HCID 7798Butyric anhydride

HCID 67632Heptafluorobutyroyl fluoride

생성물 2

HCID 9777Heptafluorobutyric acid

HCID 68035Butanoyl fluoride

실험 절차

The following run illustrates the metathetical reaction of impure heptafluorobutyryl fluoride with butyric acid in the presence of butyric anhydride to give heptafluorobutyric acid and butyryl fluoride and the recovery of products from the reaction mixture by fractional distillation.

출처 및 근거

ORD 기록: ord-f0fd27ea775447efb4ba9fb622217ab9
출처 데이터셋: uspto-grants-1977_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04038310

반응 노트

불러오는 중…