Hexamethylphosphorous triamide → HCID 178420727, 화합물

반응식

[NH:1]1[CH2:13][CH2:12][CH2:11][NH:10][CH2:9][CH2:8][NH:7][CH2:6][CH2:5][NH:4][CH2:3][CH2:2]1.CN(C)[P:16](N(C)C)N(C)C>>[N:4]12[PH:16]34[N:10]([CH2:9][CH2:8][N:7]3[CH2:6][CH2:5]1)[CH2:11][CH2:12][CH2:13][N:1]4[CH2:2][CH2:3]2

참가 물질

반응물 2

HCID 15355Hexamethylphosphorous triamide

HCID 114787231,4,7,10-Tetraazacyclotridecane

생성물 1

HCID 178420727HCID 178420727, 화합물

실험 절차

A mixture of 4.00 g (21.5 mmol) of 1,4,7,10-tetraazacyclotridecane and 3.50 g (21.5 mmol) of hexamethylphosphorous triamide is heated for 2 hr under nitrogen at 125° and then distilled under vacuum to give 3.84 g (83%) of clear, colorless, viscous liquid 1,4,8,11-tetraaza-14-phosphatetracyclo[6.5.1.04,14.011,14 ]tetradecane, bp 92° (0.30 mm).

후처리

temperatureis heated for 2 hr under nitrogen at 125°
distillationdistilled under vacuum

출처 및 근거

ORD 기록: ord-2867beae6ab64cc68fd333be26bf480c
출처 데이터셋: uspto-grants-1977_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04038312

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