Hexamethylphosphorous triamide → HCID 23414757, 화합물

HRID 259490노트

반응식

HRID 259490 반응식
[NH:1]1[CH2:14][CH2:13][CH2:12][NH:11][CH2:10][CH2:9][CH2:8][NH:7][CH2:6][CH2:5][NH:4][CH2:3][CH2:2]1.CN(C)[P:17](N(C)C)N(C)C>>[N:1]12[P:17]3[N:11]([CH2:10][CH2:9][CH2:8][N:7]3[CH2:6][CH2:5][NH:4][CH2:3][CH2:2]1)[CH2:12][CH2:13][CH2:14]2

참가 물질

3

반응물 2

HCID 15355Hexamethylphosphorous triamideHCID 63974791,4,7,11-Tetraazacyclotetradecane

생성물 1

HCID 23414757HCID 23414757, 화합물

실험 절차

A stirred mixture of 6.00 g (30 mmol) of 1,4,7,11-tetraazacyclotetradecane and 4.90 g of hexamethylphosphorous triamide is heated under nitrogen for 3 hr at 120° and then distilled in a short-path apparatus to give 5.50 g (80%) of clear, colorless liquid 1,5,9,12-tetraaza-15-phosphatricyclo[7.5.1.05,15 ]pentadecane, bp 106°-110° (0.30 mm), which solidifies on storing below 0°.

후처리

  1. temperatureis heated under nitrogen for 3 hr at 120°
  2. distillationdistilled in a short-path apparatus

출처 및 근거

ORD 기록
ord-d4afc4dfb59247bfba75ef724dd5e9a3
출처 데이터셋
uspto-grants-1977_07
특허 번호
US04038312

반응 노트

불러오는 중…