참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Allyl glycidyl ether | HCID 7838 | — |
| 반응물 | Triethoxysilane | HCID 13830 | — |
| 생성물 | gamma-Glycidoxypropyltriethoxysilane | HCID 102856 | 62.6% |
반응 단계
140 g (0.85 mol) of hydridotriethoxysilane were mixed with 100 g (0.88 mol) of allyl glycidyl ether, and 10 g of this mixture were initially introduced into a reaction vessel at 95° C. under normal pressure with 100 mg (9.5×10-5 mol) of tetrakis(1-phenyl-3-n-hexyl-1-triazenido) platinum complex. The remainder of the above mentioned was added dropwise to the mixture in the course of 80 minutes, the temperature rose to 160° C. When the addition was complete, the reaction mixture was stirred at 150° C. for an additional 30 minutes. After distillation, 3-glycidoxypropyltriethoxysilane was obtained as a colorless, liquid product in a 62.6% yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US05523436 |
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| 출처 데이터셋 | uspto-grants-1996_06 |
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| ORD ID | ord-f8784502a33042ab84b183fb01eab7f1 |
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| 출처 메모 | uspto-grants-1996_06 |
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