참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Sodium Chloride | HCID 5234 | — |
| 반응물 | Ethylbenzene | HCID 7500 | — |
| 반응물 | Dichloro(prop-2-enyl)silane | HCID 77536 | — |
| 반응물 | Aluminum(III) Chloride | HCID 6451240 | — |
| 생성물 | 3-(Ethylphenyl)-1,1-dichloro-1-silabutane | HCID 14972032 | 77.6% |
반응 단계
In the same apparatus and procedures as EXAMPLE 1, 27 g (255 mmol) of ethylbenzene and 1.1 g (9.0 mmol) of aluminum chloride were placed. The flask was then immersed in an ice water bath. To the reaction mixture was slowly added dropwise 12.0 g (85 mmol) of allyldichlorosilane and the solution was stirred for an hour. After confirming that no ethylbenzene was left by gas chromatography, 2.4 g, (413 mmol) of sodium chloride was added to reaction mixture, warmed up to 50° C. and stirred for two hours to deactivate the catalyst. Vacuum distillation of the reaction products gave 16.3 g (bp 80°-84° C./0.6 mmHg) of 3-(ethylphenyl)-1,1-dichloro-1-silabutane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05523444 |
|---|
| 출처 데이터셋 | uspto-grants-1996_06 |
|---|
| ORD ID | ord-fc9b1061219c4219a6899b476cae4f23 |
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| 출처 메모 | uspto-grants-1996_06 |
|---|
