Sodium Carbonate → Tetrafluorophthalic anhydride

HRID 259943

반응식

HRID 259943 반응식
[F:1][C:2]1[C:10]([F:11])=[C:9]([F:12])[C:8]([F:13])=[C:4]([C:5](F)=[O:6])[C:3]=1[C:14](F)=[O:15].FC1(F)C2C(=C(F)C(F)=C(F)C=2F)C(=O)[O:19]1.C(=O)([O-])[O-].[Na+].[Na+]>C1(C)C(C)=CC=CC=1>[F:1][C:2]1[C:10]([F:11])=[C:9]([F:12])[C:8]([F:13])=[C:4]2[C:5](=[O:19])[O:6][C:14](=[O:15])[C:3]=12

참가 물질

5

반응물 3

HCID 10340Sodium CarbonateHCID 11032047Perfluoro-phthalideHCID 110756133,4,5,6-tetrafluorobenzene-1,2-dicarbonyl Fluoride

생성물 1

HCID 69545Tetrafluorophthalic anhydride수율 91.5%

시약·촉매·용매 1

HCID 7237O-Xylene용매

실험 절차

Into a 500 ml glass reactor equipped with a reflux condenser and a stirrer, 100 g (0.413 mol) of the mixture (1:1) of the 3,4,5,6-tetrafluorophthaloyldifluoride and the 3,3,4,5,6,7-hexafluoro-1-[3H]-isobenzofuranone of Example 2, 43.8 g (0.413 mol) of sodium carbonate and 200 g of xylene were charged, and the mixture was reacted at 130° C. for 3 hours with vigorous stirring. Then, the inorganic substance was removed by filtration, and the residue was subjected to distillation to obtain 83.1 g of tetrafluorophthalic anhydride. The yield was 91.5%.

후처리

  1. customInto a 500 ml glass reactor equipped with a reflux condenser and a stirrer
  2. customthe mixture was reacted at 130° C. for 3 hours with vigorous stirring
  3. customThen, the inorganic substance was removed by filtration
  4. distillationthe residue was subjected to distillation

출처 및 근거

ORD 기록
ord-d4a197c767e9460fb2d107eea186e0f6
출처 데이터셋
uspto-grants-1996_06
특허 번호
US05523476

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