Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,5-Hexadiene → Bis{(2-phenylpropyl)dichlorosilyl}hexane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,5-Hexadiene | HCID 11598 | — |
| 반응물 | 3-Phenyl-1,1-dichloro-1-silabutane | HCID 123324342 | — |
| 촉매 | Chloroplatinic acid | HCID 61859 | — |
| 용매 | Isopropanol | HCID 3776 | — |
| 생성물 | Bis{(2-phenylpropyl)dichlorosilyl}hexane | HCID 22401800 | 66% |
반응 단계
In the same apparatus and procedures as EXAMPLE 1, 21.3 g (0.097 mole) of 3-(phenyl)-1,1-dichloro-1-silabutane and 100 μl of 1% chloroplatinic acid solution in isopropanol were placed and then 3.2 g (0.039 mole) of 1,5-hexadiene was added dropwise for 5 min. The solution was reacted for 15 hours at reflux under the dry nitrogen atmosphere. Vacuum distillation gave 13.4 g (185°-187° C./0.03 mmHg) of bis{(2-phenylpropyl)dichlorosilyl}hexane in 66.0% yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05527934 |
| 출처 데이터셋 | uspto-grants-1996_06 |
| ORD ID | ord-c15b152b25914a5b80fd96089064b04b |
| 출처 메모 | uspto-grants-1996_06 |