Water → 1-(1-Ethylpropylamino)-4-bromanthraquinone

HRID 260816

반응식

HRID 260816 반응식
[CH2:1]([CH:3]([NH:6][C:7]1[C:20]2[C:19](=[O:21])[C:18]3[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=3)[C:12](=[O:22])[C:11]=2[CH:10]=[CH:9][CH:8]=1)[CH2:4][CH3:5])[CH3:2].O.S([O-])([O-])=O.[Na+].[Na+].[Br:30]Br>C(O)(=O)C>[CH2:1]([CH:3]([NH:6][C:7]1[C:20]2[C:19](=[O:21])[C:18]3[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=3)[C:12](=[O:22])[C:11]=2[C:10]([Br:30])=[CH:9][CH:8]=1)[CH2:4][CH3:5])[CH3:2]

참가 물질

6

반응물 4

HCID 962WaterHCID 24408Bromine3회HCID 24437Sodium SulfiteHCID 229162751-(1-Ethylpropylamino)anthraquinone

생성물 1

HCID 229162741-(1-Ethylpropylamino)-4-bromanthraquinone

시약·촉매·용매 1

HCID 176Acetic Acid용매2회

실험 절차

EPAQ (20.02 g) was dissolved in hot acetic acid. In a separate flask, bromine (12.03 g) was dissolved in acetic acid (ca. 10 mL). The bromine solution was slowly added to the dye solution. The reaction was allowed to proceed for 1/2 hour, with occasional shaking. The reaction mixture was poured into water (600 mL), and aqueous sodium sulfite was added to discharge the bromine. The aqueous solution was decanted off. The solid was dissolved in methylene chloride and then concentrated and slowly added to cold methanol whereupon a solid precipitated.

후처리

  1. additionwas added
  2. customThe aqueous solution was decanted off
  3. dissolutionThe solid was dissolved in methylene chloride
  4. concentrationconcentrated
  5. additionslowly added to cold methanol whereupon a solid
  6. customprecipitated

출처 및 근거

ORD 기록
ord-b5f6c7cee48b4300997d734cdd52d931
출처 데이터셋
uspto-grants-1996_06
특허 번호
US05530053

연결된 노트

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