Nitric Acid → Dibismuth molybdenum hexaoxide

HRID 26126노트

반응식

HRID 26126 반응식
[N+]([O-])(O)=[O:2].[N+]([O-])([O-])=[O:6].[Bi+3:9].[N+]([O-])([O-])=[O:11].[N+]([O-])([O-])=[O:15].N.N.N.N.N.N.[OH2:24].O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo:48].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[NH4+].[OH-]>O>[O-2:2].[O-2:6].[O-2:11].[O-2:15].[O-2:24].[O-2:2].[O-2:2].[O-2:2].[O-2:2].[Mo:48].[Mo:48].[Bi+3:9].[Bi+3:9]

참가 물질

6

반응물 4

HCID 944Nitric AcidHCID 14923Ammonium HydroxideHCID 25488Azane;molybdenum;tetracosahydrateHCID 107711Bismuth nitrate

생성물 1

HCID 159680Dibismuth molybdenum hexaoxide

시약·촉매·용매 1

HCID 962Water용매

실험 절차

14.55 g Bi(NO3)3.5H2O was dissolved in 100 ml. of a 10 percent HNO3 aqueous solution. 7.95 g of (NH4)Mo7O24.4H2O was dissolved in 100 ml. H2O with heating. The bismuth nitrate solution was then slowly added to the ammonium heptamolybdate solution with constant stirring. The pH was then adjusted to 2.5 to 3 by the addition of NH4OH. The mixture was stirred for about one hour, thereby yielding a bismuth molybdate slurry.

출처 및 근거

ORD 기록
ord-81df126905674916a2ca429adb571ac4
출처 데이터셋
uspto-grants-1979_04
특허 번호
US04148757

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