alpha-(p-Bromophenyl)-alpha-phenyl-1-(toluene-p-sulphonyl)imidazole-2-methanol → bis(4-bromophenyl)(1H-imidazol-2-yl)methanol

HRID 261940

반응식

HRID 261940 반응식
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([C:25]2[CH:30]=[CH:29][C:28]([Br:31])=[CH:27][CH:26]=2)([C:10]2[N:11](S(C3C=CC(C)=CC=3)(=O)=O)[CH:12]=[CH:13][N:14]=2)[OH:9])=[CH:4][CH:3]=1.BrC1C=CC(C(C2C=CC=CC=2)(C2N(S(C3C=CC(C)=CC=3)(=O)=O)C=CN=2)O)=CC=1>>[Br:1][C:2]1[CH:3]=[CH:4][C:5]([C:8]([C:25]2[CH:30]=[CH:29][C:28]([Br:31])=[CH:27][CH:26]=2)([C:10]2[NH:14][CH:13]=[CH:12][N:11]=2)[OH:9])=[CH:6][CH:7]=1

참가 물질

3

반응물 2

HCID 11838798alpha-(p-Bromophenyl)-alpha-phenyl-1-(toluene-p-sulphonyl)imidazole-2-methanolHCID 12433921HCID 12433921, 화합물

생성물 1

HCID 12433872bis(4-bromophenyl)(1H-imidazol-2-yl)methanol

실험 절차

Using the procedure described in Example IB but substituting an equivalent amount of α,α-bis(p-bromophenyl)-1-(toluene-p-sulphonyl)imidazole-2-methanol for the α-(p-bromophenyl)-α-phenyl-1-(toluene-p-sulphonyl)imidazole-2-methanol, α,α-bis(p-bromophenyl)imidazole-2-methanol was obtained. Its melting point was 192°-194° C. after crystallisation from isopropyl alcohol.

출처 및 근거

ORD 기록
ord-2d86235c0e684be8a9c7bf6c439e6a00
출처 데이터셋
uspto-grants-1979_05
특허 번호
US04152441

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