Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Phenylindole → 3-phenyl-2,3-dihydro-1H-indole
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Phenylindole | HCID 96502 | — |
| 반응물 | Trifluoroborane Hydrofluoride | HCID 9855450 | — |
| 촉매 | Palladium | HCID 23938 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 3-phenyl-2,3-dihydro-1H-indole | HCID 10932353 | 47% |
반응 단계
A mixture of 4.0 g of 3-phenylindole, 80 ml of 86% ethanol, 35 ml of 48% hydrofluoroboric acid and 0.25 g of 10% Pd/C was hydrogenated at 60 p.s.i. and 60° C. for 18 hours. The reaction mixture was worked up as in Example 2 and 1.9 g of pure 3-phenylindoline was obtained.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04153789 |
| 출처 데이터셋 | uspto-grants-1979_05 |
| ORD ID | ord-0a4712bbb69d4e66aa50b5d642860249 |
| 출처 메모 | uspto-grants-1979_05 |