Nitrobenzene → 1,7-Dinitroanthraquinone

반응식

[N+:1]([C:4]1[CH:17]=[CH:16][C:15]2[C:14](=[O:18])C3C(=CC=CC=3)[C:7](=[O:19])[C:6]=2[C:5]=1[N+]([O-])=O)([O-:3])=[O:2].[N+:23]([C:26]1[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1)([O-:25])=[O:24]>>[N+:23]([C:26]1[C:31]2[C:7](=[O:19])[C:6]3[C:15](=[CH:16][CH:17]=[C:4]([N+:1]([O-:3])=[O:2])[CH:5]=3)[C:14](=[O:18])[C:30]=2[CH:29]=[CH:28][CH:27]=1)([O-:25])=[O:24]

참가 물질

반응물 2

HCID 7416Nitrobenzene

HCID 425969,10-Anthracenedione, 1,2-dinitro-

생성물 1

HCID 741471,7-Dinitroanthraquinone

실험 절차

100 g of dinitroanthraquinone mixture of the composition described in Example 1 (A) are employed and stirred with B ml of nitrobenzene at C° C. for A hours and the precipitate is filtered off at C° C., washed with 50 ml of nitrobenzene and dried. D g of 1,7-dinitro-anthraquinone of the composition E are obtained.

후처리

waitfor A hours
filtrationthe precipitate is filtered off at C° C
wash, washed with 50 ml of nitrobenzene
customdried

출처 및 근거

ORD 기록: ord-9d983bda8cdc45b2bf3f10bf3b9057cb
출처 데이터셋: uspto-grants-1979_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04155921

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