Benzene → Acetyl chloride, 2,2'-[1,2-phenylenebis(oxy)]bis-

HRID 263276노트

반응식

HRID 263276 반응식
[C:1]([Cl:6])(=[O:5])[C:2](Cl)=[O:3].[CH:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1>>[Cl:6][C:1]([CH2:2][O:3][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=1[O:3][CH2:2][C:1]([Cl:6])=[O:5])=[O:5]

참가 물질

3

반응물 2

HCID 241BenzeneHCID 65578Oxalyl chloride

생성물 1

HCID 11076276Acetyl chloride, 2,2'-[1,2-phenylenebis(oxy)]bis-

실험 절차

30 g. Of the above acid are added to a mixture of 200 ml. anhydrous benzene. Then 35 g. oxalylchloride are added, the flask being protected by a calcium chloride tube. The mixture is stirred for four days and the diacid progressively dissolves as it is being transformed into the corresponding dichloride. The solution is then evaporated to dryness (without heating) leaving a brownish solid residue which is recrystallized from a mixture of chloroform-benzene giving white crystals.

후처리

  1. additionOf the above acid are added to a mixture of 200 ml
  2. customthe flask being protected by a calcium chloride tube
  3. customThe solution is then evaporated to dryness (without heating)
  4. customleaving a brownish solid residue which
  5. customis recrystallized from a mixture of chloroform-benzene giving white crystals

출처 및 근거

ORD 기록
ord-218b80ad683644b985ae91ef1ed4683b
출처 데이터셋
uspto-grants-1979_05
특허 번호
US04156683

반응 노트

불러오는 중…