Sodium Chloride → HCID 21322899, 화합물

HRID 26355

반응식

HRID 26355 반응식
[C:1]1([P:7](=[O:10])([OH:9])[OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:11][S:12](O)(=[O:14])=[O:13].[Cl-].[Na+]>>[P:7]([C:1]1[CH:6]=[C:5]([S:12]([Cl:11])(=[O:14])=[O:13])[CH:4]=[CH:3][CH:2]=1)([OH:9])([OH:8])=[O:10]

참가 물질

4

반응물 3

HCID 5234Sodium ChlorideHCID 15295Phenylphosphonic Acid4회HCID 24638Chlorosulfonic acid4회

생성물 1

HCID 21322899HCID 21322899, 화합물

반응 조건

온도
140 °C

실험 절차

The preparation was undertaken as a modification of the process for forming 3-carboxybenzenesulfonyl chloride as reported in J. Chem. Soc. (C), page 11 et seq. (1968) by R. J. W. Cremlyn. Phenylphosphonic acid was added in portions to chlorosulfonic acid; about 10 moles of chlorosulfonic acid per mole of phenylphosphonic acid were employed. The initial mixing step was exothermic, causing the temperature of the mixture to rise to about 90° C. After completion of the addition of the phenylphosphonic acid to the chlorosulfonic acid, the reaction mixture was heated to about 140° C. for about two hours. Reaction proceeded according to the equation ##STR5## Attempts to lower the molar ratio of chlorosulfonic acid: phenylphosphonic acid, by addition of sodium chloride (to remove sulfuric acid from the reaction mixture), caused uncontrollable frothing.

후처리

  1. additionThe initial mixing step
  2. customto rise to about 90° C
  3. customReaction
  4. customto remove sulfuric acid from the reaction mixture),

출처 및 근거

ORD 기록
ord-2f67df89272540589f303ba72bc7384c
출처 데이터셋
uspto-grants-1979_04
특허 번호
US04150021

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