Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Butanol → Di-t-Butyl Diperoxyfumarate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Butanol | HCID 263 | — |
| 반응물 | tert-Butyl hydroperoxide | HCID 6410 | — |
| 반응물 | Fumaryl chloride | HCID 5325504 | — |
| 반응물 | Peroxyfumarate | HCID 131720069 | — |
| 용매 | Alpha-Methylstyrene | HCID 7407 | — |
| 생성물 | Di-t-Butyl Diperoxyfumarate | HCID 5880646 | — |
반응 단계
Since the actual yield and the actual Act[O] were 38.0 g and 7.31%, respectively, the uncorrected yield was 77.2% and the yield corrected for Act[O] (i.e., the corrected yield) was 79.1%. The higher than expected Act[O] indicated that t-butyl hydroperoxide was somewhat more reactive towards fumaryl chloride than the n-butanol was. The first peroxyfumarate composition (Preparation 1) was found to have a half-life of 19.0 hours at 100° C. in alpha-methylstyrene based on conventional determination procedures.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05644004 |
| 출처 데이터셋 | uspto-grants-1997_07 |
| ORD ID | ord-2c441b6fc7d14d1cae613410fbc302b3 |
| 출처 메모 | uspto-grants-1997_07 |