1,2-Dimethoxyethane → Anthracene

HRID 2637

반응식

HRID 2637 반응식
C(COC)OC.[CH:7]1[C:20]2[C:11](=[CH:12][C:13]3[C:18]([CH:19]=2)=[CH:17][CH:16]=[CH:15][CH:14]=3)[CH:10]=[CH:9][CH:8]=1.[K]>CN1C(=O)CCC1>[CH:10]1[C:11]2[C:20](=[CH:19][C:18]3[C:13]([CH:12]=2)=[CH:14][CH:15]=[CH:16][CH:17]=3)[CH:7]=[CH:8][CH:9]=1

참가 물질

4

반응물 2

HCID 80711,2-DimethoxyethaneHCID 86741178Potassium Anthracene

생성물 1

HCID 8418Anthracene

시약·촉매·용매 1

HCID 13387N-methyl-2-pyrrolidone용매

실험 절차

A KAn solution is prepared as described in Example 20. The monoglyme is allowed to evaporate and the solid potassium anthracide complex collected. The melting point of the potassium anthracide crystals is >300° C. The dark-blue crystals turn white on exposure to air as a result of the radical-anion oxidation. Potassium anthracene salt is added to a solution of anhydrous NMP to give a 0.05M anthracene radical-anion solution resulting in the characteristic deep blue-black coloration of the solution. The KAn is stable in NMP. A sample of PTFE is treated in this bath and Pd seeded and electroless Cu subsequently plated as described in Example 17 with similar results.

후처리

  1. customA KAn solution is prepared
  2. customto evaporate
  3. customthe solid potassium anthracide complex collected
  4. customis >300° C
  5. customa result of the radical-anion oxidation

출처 및 근거

ORD 기록
ord-cdd0d0c2b859493db6e0040c9ec93e28
출처 데이터셋
uspto-grants-1998_03
특허 번호
US05730890

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