Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diethyl Ether → 9b-Allyl-8-methoxy-3-methyl-5,9b-dihydrobenz[e]indoline
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diethyl Ether | HCID 3283 | — |
| 반응물 | Lithium Hydroxide | HCID 3939 | — |
| 반응물 | Picric Acid | HCID 6954 | — |
| 반응물 | Picrate | HCID 4432340 | — |
| 반응물 | 2,3-Dihydro-1h-benzo[e]indole | HCID 11147965 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 9b-Allyl-8-methoxy-3-methyl-5,9b-dihydrobenz[e]indoline | HCID 23330780 | — |
반응 단계
The benz[e]indoline IIa regenerated from the picrate XIVd (X=picric acid) as follows: A mixture of finely powder picrate (10 mmol), 1 N aqueous lithium hydroxide (50 ml), ethanol (20 ml) and ether (100 ml) in a separatory funnel was shaken until all the picrate had dissolved. The ether phase was washed with water and, after drying, was evaporated to dryness to give the free base IIa quantitatively.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04150032 |
| 출처 데이터셋 | uspto-grants-1979_04 |
| ORD ID | ord-16a17a0b36e14ed6b91cdc45dfc700a2 |
| 출처 메모 | uspto-grants-1979_04 |