Benzyl Bromide → 3-benzylthio-11H-s-triazolo[3,4-b][3]benzazepine

HRID 26509노트

반응식

HRID 26509 반응식
[N:1]1[NH:2][C:3](=[S:15])[N:4]2[CH:10]=[CH:9][C:8]3[CH:11]=[CH:12][CH:13]=[CH:14][C:7]=3[CH2:6][C:5]=12.[CH2:16](Br)[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1.C[O-].[Na+]>>[CH2:16]([S:15][C:3]1[N:4]2[C:5]([CH2:6][C:7]3[CH:14]=[CH:13][CH:12]=[CH:11][C:8]=3[CH:9]=[CH:10]2)=[N:1][N:2]=1)[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1

참가 물질

4

반응물 3

HCID 7498Benzyl BromideHCID 10942334Sodium MethoxideHCID 130724232,11-dihydro-3H-s-triazolo[3,4-b][3]benzazepine-3-thione

생성물 1

HCID 213233223-benzylthio-11H-s-triazolo[3,4-b][3]benzazepine

실험 절차

The reaction of 2,11-dihydro-3H-s-triazolo[3,4-b][3]benzazepine-3-thione with benzyl bromide in the presence of sodium methoxide gave 3-benzylthio-11H-s-triazolo[3,4-b][3]benzazepine.

출처 및 근거

ORD 기록
ord-c1a23c7de5064314ae451a7aaebeed45
출처 데이터셋
uspto-grants-1979_04
특허 번호
US04150139

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