참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Azobisisobutyronitrile | HCID 6547 | — |
| 반응물 | Methyl Acrylate | HCID 7294 | — |
| 반응물 | Benzyl methacrylate | HCID 17236 | — |
| 반응물 | Methyl 3-mercaptopropionate | HCID 18050 | — |
| 반응물 | 2-Methyldecane | HCID 23415 | — |
| 생성물 | 3,6-Dimethyl-3-octanol | HCID 9027 | — |
반응 단계
A mixed solution of the whole amount of the above-described resin grain dispersion (as seed) and 10 g of Dispersion Stabilizing Resin (Q-1) was heated to a temperature of 60° C. under nitrogen gas stream with stirring. To the mixture was added dropwise a mixture of 85 g of benzyl methacrylate, 15 g of methyl acrylate, 1.0 g of methyl 3-mercaptopropionate, 0.8 g of AIVN and 200 g of Isopar H over a period of 2 hours, followed by further reacting for 2 hours. Then 0.8 g of AIVN was added to the reaction mixture, the temperature thereof was raised to 70° C., and the reaction was conducted for 2 hours. Further, 0.6 g of AIVN was added thereto, followed by reacting for 3 hours. After cooling, the reaction mixture was passed through a nylon cloth of 200 mesh to obtain a white dispersion which was a latex of good monodispersity having a polymerization ratio of 98% and an average grain diameter of 0.25 μm.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US05648190 |
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| 출처 데이터셋 | uspto-grants-1997_07 |
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| ORD ID | ord-ae589cc75aba45d6af1a9ea5840a6d3b |
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| 출처 메모 | uspto-grants-1997_07 |
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