3,5-Dichloropentan-2-one → 3-Thiocyanato-5-chloro-2-pentanone

HRID 265637

반응식

HRID 265637 반응식
Cl[CH:2]([CH2:6][CH2:7][Cl:8])[C:3](=[O:5])[CH3:4].[C:9]([S-:11])#[N:10].[Na+]>CC(CC)=O>[S:11]([CH:2]([CH2:6][CH2:7][Cl:8])[C:3](=[O:5])[CH3:4])[C:9]#[N:10]

참가 물질

4

반응물 2

HCID 940323,5-Dichloropentan-2-oneHCID 516871Sodium thiocyanate

생성물 1

HCID 108776933-Thiocyanato-5-chloro-2-pentanone수율 96.3%

시약·촉매·용매 1

HCID 6569Methyl Ethyl Ketone용매

실험 절차

A solution of 155.5 g (1 mole) of 3,5-dichloro-2-pentanone with 83 g (1.024 moles) of sodium rhodanide in 1 litre of methyl-ethyl-ketone is boiled for 1 hour under stirring. Then the procedure described in Example 1 is followed. 171 g (96.2%) of 3-thiocyanato-5-chloro-2-pentanone are obtained, which after distillation identical in all respect with the product of Example 1.

출처 및 근거

ORD 기록
ord-0597742d06cf4b7aab92ee2fd1c449ff
출처 데이터셋
uspto-grants-1997_07
특허 번호
US05648498

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