Hydrogen Peroxide → 2,3-Dihydroxybutanedioic Acid

HRID 26584

반응식

HRID 26584 반응식
C(O)(=O)/C=C\C(O)=[O:5].OO.[O:11]1[CH:16]([C:17]([OH:19])=[O:18])[CH:12]1[C:13]([OH:15])=[O:14]>>[CH:16]([OH:11])([C:17]([OH:19])=[O:18])[CH:12]([OH:5])[C:13]([OH:15])=[O:14]

참가 물질

4

실험 절차

Thus free maleic acid is reacted in aqueous solution with hydrogen peroxide in the presence of alkali tungstates or molybdates, the intermediate epoxysuccinic acid formed hydrolyzed by boiling and then the racemic acid formed crystallized out of the hydrolysis solution, see Church and Blumberg, "Ind. Eng. Chem.", Vol. 43 (8) pages 1780 to 1786. The mother liquor of the racemic acid crystallization is again returned into the reaction step.

출처 및 근거

ORD 기록
ord-827bc7b9db5247158b5c97acb2fc6683
출처 데이터셋
uspto-grants-1979_04
특허 번호
US04150241

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