Tributylamine → 4-(Chloromethyl)benzyltri-n-butylammonium chloride

HRID 266003

반응식

HRID 266003 반응식
[CH2:1]([N:5]([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[Cl:14][CH2:15][C:16]1[CH:21]=[CH:20][C:19]([CH2:22][Cl:23])=[CH:18][CH:17]=1>CO>[Cl-:14].[Cl:23][CH2:22][C:19]1[CH:20]=[CH:21][C:16]([CH2:15][N+:5]([CH2:6][CH2:7][CH2:8][CH3:9])([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:1][CH2:2][CH2:3][CH3:4])=[CH:17][CH:18]=1

참가 물질

4

반응물 2

HCID 7622TributylamineHCID 12171alpha,alpha'-Dichloro-p-xylene

생성물 1

HCID 867489774-(Chloromethyl)benzyltri-n-butylammonium chloride

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

A mixture of tri-n-butylamine (6 g, 32.2 mmol) and α,α'-dichloro-p-xylene (8 g, 46.0 mmol) in methanol (50 mL) was refluxed for 15 h after which time TLC examination showed completion of the reaction. Methanol was removed under reduced pressure to give an oily residue. The colorless oil was washed several times with toluene and hexane and then dried. The product obtained was used without further purification.

후처리

  1. temperaturewas refluxed for 15 h after which time TLC examination
  2. customcompletion of the reaction
  3. customMethanol was removed under reduced pressure
  4. customto give an oily residue
  5. washThe colorless oil was washed several times with toluene and hexane
  6. customdried
  7. customThe product obtained
  8. customwas used without further purification

출처 및 근거

ORD 기록
ord-94af520978af41eebcbf90b1e0360f67
출처 데이터셋
uspto-grants-1997_07
특허 번호
US05650099

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