Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Imidazole → N-(1-Hexylheptyl)perylene-3,4-dicarboximide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Imidazole | HCID 795 | — |
| 반응물 | Water | HCID 962 | — |
| 반응물 | 3,4,9,10-Perylenetetracarboxylic dianhydride | HCID 67191 | — |
| 반응물 | Tridecan-7-amine | HCID 574991 | — |
| 반응물 | N-(2,5-Di-t-butylphenyl)perylene-3,4-dicarboximide | HCID 11081772 | — |
| 촉매 | Zinc acetate (USP) | HCID 2724192 | — |
| 생성물 | N-(1-Hexylheptyl)perylene-3,4-dicarboximide | HCID 11443487 | — |
반응 단계
1.2 g (3.1 mmol) of perylene-3,4,9, 10-tetracarboxylic dianhydride, 6.2 g of imidazole, 470 mg (2.36 mmol) of 7-aminotridecane (prepared according to J. Prakt. Chem. 1980, 322, 261), 150 mg (0.68 mmol) of zinc acetate dihydrate and 3.0 ml (170 mmol) of water are heated in an autoclave (100 ml) at 190° C. for 24 h. Workup is analogous to that used in the preparation of 2b. Yield 1.25 g (27%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05650513 |
| 출처 데이터셋 | uspto-grants-1997_07 |
| ORD ID | ord-67282756a1ef482bb6fc7c4ab8f27489 |
| 출처 메모 | uspto-grants-1997_07 |