Nitric Acid → 5-Nitronaphthalene-1,4-dione

HRID 267249

반응식

HRID 267249 반응식
[C:1]1(=[O:12])[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[C:4](=[O:11])[CH:3]=[CH:2]1.S(=O)(=O)(O)O.[N+:18]([O-])([OH:20])=[O:19]>O>[N+:18]([C:6]1[CH:7]=[CH:8][CH:9]=[C:10]2[C:5]=1[C:4](=[O:11])[CH:3]=[CH:2][C:1]2=[O:12])([O-:20])=[O:19]

참가 물질

5

반응물 3

HCID 944Nitric AcidHCID 1118Sulfuric AcidHCID 85301,4-Naphthoquinone

생성물 1

HCID 123364025-Nitronaphthalene-1,4-dione

시약·촉매·용매 1

HCID 962Water용매

실험 절차

The same procedure as in Example 1 was repeated except that 10.0 g of 1,4-naphthoquinone was added to 200 g of a mixed acid consisting of 83 percent by weight of sulfuric acid, 4 percent by weight of nitric acid and 13 percent by weight of water with maintaining a temperature of 5° to 10°C, to obtain 8.9 g of brown-colored crude 5-nitro-1,4-naphthoquinone of a melting point of 140°C. The D.V.S. of the reaction mixture after reaction was 6.1. The crude product was purified to obtain the similar results with Example 1.

후처리

  1. temperaturewith maintaining a temperature of 5° to 10°C

출처 및 근거

ORD 기록
ord-223a5c2c4327444aa95e12bb1f641d55
출처 데이터셋
uspto-grants-1976_03
특허 번호
US03941815

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