Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
N-Bromoacetamide → Sodium (2-hydroxy-1-bromopropyl)-phosphonate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | N-Bromoacetamide | HCID 4353 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | P-(1Z)-1-Propen-1-ylphosphonic acid | HCID 6436667 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Sodium (2-hydroxy-1-bromopropyl)-phosphonate | HCID 86733120 | — |
반응 단계
10.8 g. of cis-propenylphosphonic acid is dissolved in 50 ml. of water and the pH of the solution is adjusted to 4.2 by the addition of 2.5 N sodium hydroxide. 13.8 g. of N-bromoacetamide is added and the suspension is stirred at room temperature. The reaction is complete when the N-bromoacetamide is in solution and the mixture is negative to starch-iodide paper. The solution is lyophilized and the residue is triturated several times with chloroform to give sodium (2-hydroxy-1-bromopropyl)-phosphonate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03943153 |
| 출처 데이터셋 | uspto-grants-1976_03 |
| ORD ID | ord-d3df9ff839424b4a863354e31b5ebf93 |
| 출처 메모 | uspto-grants-1976_03 |