Diethyl oxalacetate → HCID 86733114, 화합물

HRID 268010노트

반응식

HRID 268010 반응식
[N:1]([C:4]1[CH:11]=[CH:10][CH:9]=[CH:8][C:5]=1[CH:6]=O)=[N+:2]=[N-:3].[CH2:12]([O:14][C:15](=[O:24])[CH2:16][C:17]([C:19]([O:21][CH2:22][CH3:23])=[O:20])=O)[CH3:13].[CH2:25]([O:27][C:28](=[O:33])/[CH:29]=[C:30](\[NH2:32])/[CH3:31])[CH3:26]>C(O)C>[CH2:25]([O:27][C:28]([C:29]1[CH:6]([C:5]2[CH:8]=[CH:9][CH:10]=[CH:11][C:4]=2[N:1]=[N+:2]=[N-:3])[C:16]([C:15]([O:14][CH2:12][CH3:13])=[O:24])=[C:17]([C:19]([O:21][CH2:22][CH3:23])=[O:20])[NH:32][C:30]=1[CH3:31])=[O:33])[CH3:26]

참가 물질

5

반응물 3

HCID 66951Diethyl oxalacetateHCID 6437562-Butenoic acid, 3-amino-, ethyl ester, (2Z)-HCID 108880602-Azidobenzaldehyde

생성물 1

HCID 86733114HCID 86733114, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

A solution of 14.7 g of 2-azidobenzaldehyde, 19 g of oxalacetic acid diethyl ester and 13 g of β-aminocrotonic acid ethyl ester in 40 ccs of ethanol is heated to the boil overnight and evaporated in vacuo. Yellow-brown oil.

후처리

  1. customevaporated in vacuo

출처 및 근거

ORD 기록
ord-8d1bba2a2f9f4113acc7effd7ae45885
출처 데이터셋
uspto-grants-1976_03
특허 번호
US03946027

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