Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetone → 3,3,5-Trimethylcyclohexanone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetone | HCID 180 | — |
| 반응물 | Sulfuric acid magnesium salt (1:1) | HCID 24083 | — |
| 반응물 | 1-Amino-3,3,5-trimethylcyclohexyl hydroperoxide | HCID 21510183 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 3,3,5-Trimethylcyclohexanone | HCID 13398 | — |
반응 단계
Acetone (11.6 g.) in ethanol (50 c.c.) was stirred at below 0°C and 1-amino-3,3,5-trimethylcyclohexyl hydroperoxide (17.3 g.; 80% pure) added. After stirring for ca. 1 hour the solid had dissolved. To the solution was added magnesium sulphate and it was stored at 0° overnight. Filtration and distillation gave acetone and dihydroisophorone (probably containing some symmetrical amino-peroxide ##EQU20## and a product (2.2 g.), b.p. 75° - 78°/1.0 mm, had a peroxide equivalent 239.4 and gave N, 6.3% an elemental analysis.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03947406 |
| 출처 데이터셋 | uspto-grants-1976_03 |
| ORD ID | ord-02c65e8f0026420384ed4df9a6c34bff |
| 출처 메모 | uspto-grants-1976_03 |