Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ammonia acetate → 3,3,5-Trimethylcyclohexanone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ammonia acetate | HCID 12432 | — |
| 반응물 | 3,3,5-Trimethylcyclohexanone | HCID 13398 | — |
| 반응물 | 1-Aminocyclohexyl hydroperoxide | HCID 19380058 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | Cyclohexanone | HCID 7967 | — |
| 생성물 | 3,3,5-Trimethylcyclohexanone | HCID 13398 | 64.3% |
반응 단계
1-Aminocyclohexyl hydroperoxide (13.1 g.), dihydroisophorone (14 g.), methanol (25 cc.) and ammonia acetate (1.0 g.) were mixed, stored at 0°C overnight and worked up as in the previous Example. Distillation gave cyclohexanone and dihydroisophorone (9.0 g.), an intermediate fraction (3.2 g.), b.p. below 100°C/0.7 mm., Hg., a fraction (8.1 g.), b.p. 110° - 114° 10.7 mm. of 3,3,5'-trimethyl-1,1'-peroxy-dicyclohexylamine (peroxide equivalent, 234; perchloric acid equivalent, 245; and residue (1.5 g.).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03947406 |
| 출처 데이터셋 | uspto-grants-1976_03 |
| ORD ID | ord-e8663b9339e748698fc7f0e0479767fa |
| 출처 메모 | uspto-grants-1976_03 |