Chlorotriethylsilane → 3-Triethylsilyl-2-oxazolidinone

HRID 268304

반응식

HRID 268304 반응식
[CH2:1]([Si:3]([CH2:7][CH3:8])([CH2:5][CH3:6])Cl)[CH3:2].[O:9]1[CH2:13][CH2:12][NH:11][C:10]1=[O:14]>>[CH2:1]([Si:3]([CH2:7][CH3:8])([CH2:5][CH3:6])[N:11]1[CH2:12][CH2:13][O:9][C:10]1=[O:14])[CH3:2]

참가 물질

3

반응물 2

HCID 13819ChlorotriethylsilaneHCID 739492-Oxazolidinone

생성물 1

HCID 214547763-Triethylsilyl-2-oxazolidinone

실험 절차

Following the previous example, but replacing the trimethylchlorosilane with triethylchlorosilane (63.3 g; 0.42 mol) and operating under similar conditions, the result is the compound of the above heading; a colorless fluid liquid, obtained with a similar yield. 2-oxazolidinone, calculated: 42.82%; found; 42.70%. Distills at 100°C between 2 and 4 mm.

후처리

  1. customa colorless fluid liquid, obtained with a similar yield
  2. distillationDistills at 100°C between 2 and 4 mm

출처 및 근거

ORD 기록
ord-158e83453e7449beb90a25edd87432d5
출처 데이터셋
uspto-grants-1976_03
특허 번호
US03947465

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