Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzenamine, N-sulfinyl- → N-sulfinyl-N-'-(3-trifluoromethylphenyl)-hydrazine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzenamine, N-sulfinyl- | HCID 70739 | — |
| 반응물 | (3-(Trifluoromethyl)phenyl)hydrazine | HCID 98650 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | N-sulfinyl-N-'-(3-trifluoromethylphenyl)-hydrazine | HCID 21552090 | 64% |
반응 단계
20 g (0.113 mole) of 3-trifluoromethyl-phenylhydrazine were dissolved in 50 ml of methanol with addition of 5 ml of acetic acid; 16 g (0.115 mole) of sulfinylaniline were added dropwise at a temperature of 22°C. The product crystallized out while the temperature rose to about 30°C. After filtration and drying, 16 g of N-sulfinyl-N-' -(3-trifluoromethylphenyl)-hydrazine of melting point 100°C were obtained. The yield was 64% of theory.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03947513 |
| 출처 데이터셋 | uspto-grants-1976_03 |
| ORD ID | ord-e391a39ac46b42f3ad518b84f023b3fd |
| 출처 메모 | uspto-grants-1976_03 |