1-Methylimidazole → Imidazolium cation

HRID 269402

반응식

HRID 269402 반응식
[Br:1][CH2:2][CH2:3][O:4][C:5]1[C:9]([CH3:10])=[CH:8][S:7][CH:6]=1.C[N:12]1[CH:16]=[CH:15][N:14]=[CH:13]1>>[Br:1][CH2:2][CH2:3][O:4][C:5]1[C:9]([CH3:10])=[CH:8][S:7][CH:6]=1.[NH+:12]1[CH:16]=[CH:15][NH:14][CH:13]=1

참가 물질

4

반응물 2

HCID 13901-Methylimidazole2회HCID 220163383-(2-Bromoethoxy)-4-methylthiophene3회

생성물 2

HCID 444234Imidazolium cationHCID 220163383-(2-Bromoethoxy)-4-methylthiophene

실험 절차

Similarly, monomer 2 is prepared from 3-(2-bromoethoxy)-4-methylthiophene (compound 4) and 1-methylimidazole (Aldrich Co.) (see Scheme 2). Compound 4 is prepared according to the procedure developed by Leclerc et al. (Faïd, K.; Leclerc, M. J. Chem. Soc., Chem. Commun., 2761, (1996)). The quaternization reaction between 1-methylimidazole and compound 4, provides the desired monomer imidazolium salt 2. (Lucas, P.; Mehdi, N. E.; Ho, H. A.; Belanger, D.; Breau, L. Synthesis, 9, 1253, (2000)).

출처 및 근거

ORD 기록
ord-0f94149835124265b70e8f0810a9e23c
출처 데이터셋
uspto-grants-2008_11
특허 번호
US07446213B2

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