Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Trichlorosilane → 13-Tetradecenyl trichlorosilane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Trichlorosilane | HCID 24811 | — |
| 반응물 | Tetradeca-1,13-diene | HCID 30875 | — |
| 촉매 | Mercury | HCID 23931 | — |
| 생성물 | 13-Tetradecenyl trichlorosilane | HCID 10131540 | 30.3% |
반응 단계
A stirred mixture of 6.8 g (0.05 mole) trichlorosilane and 19.6 g (0.1 mole) 1,13-tetradecadiene was irradiated in a closed quartz tube at 45° C. for 72 hours with two Hanau 70 watt high pressure mercury immersion lamps, emitting a broad spectrum of ultraviolet light. The resulting crude product was then fractionated to yield 5 g (25%) of 13-tetradecenyl trichlorosilane as the monoadduct.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04220556 |
| 출처 데이터셋 | uspto-grants-1980_09 |
| ORD ID | ord-8e527906fad14278b2fcf42dbc64f754 |
| 출처 메모 | uspto-grants-1980_09 |