3-Methyl-3-oxetanemethanol → HCID 68829387, 화합물

HRID 271629

반응식

HRID 271629 반응식
C[C:2]1(CO)[CH2:5][O:4][CH2:3]1.[CH3:8][C:9]([C:11]1[CH:16]=[CH:15][CH:14]=[C:13](C([N:20]=[C:21]=[O:22])(C)C)[CH:12]=1)=C>>[CH3:8][CH:3]1[CH2:2][CH2:5][O:4]1.[C:21](=[O:22])([OH:4])[NH2:20].[CH2:8]=[CH:9][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

참가 물질

3

반응물 2

HCID 1378373-Methyl-3-oxetanemethanolHCID 6041521-(1-Isocyanato-1-methylethyl)-3-(1-methylethenyl)benzene

생성물 1

HCID 68829387HCID 68829387, 화합물

반응 조건

온도
65 °C

실험 절차

3-Methyl-3-oxetane methanol (20.00 g, 0.1958 mole) and m-TMI (39.49 g, 0.1958 mole) were combined in a 250-ml four-neck round bottom flask equipped with a condenser, mechanical mixer, thermometer, nitrogen purge and oil bath. The reaction was placed under nitrogen with stirring and heated to 65° C. in the oil bath. A single drop of dibutyltin dilaurate was added and within 5 hours the reaction was complete based on depletion of the FT-IR isocyanate peak (2254 cm−1). The product was then removed from the flask as a colorless liquid with a viscosity of 21,000 cPs.

후처리

  1. customequipped with a condenser
  2. custommechanical mixer, thermometer, nitrogen purge
  3. additionA single drop of dibutyltin dilaurate was added and within 5 hours the reaction
  4. customThe product was then removed from the flask as a colorless liquid with a viscosity of 21,000 cPs

출처 및 근거

ORD 기록
ord-9f2dbb30cce642bf844fae54bdac4633
출처 데이터셋
uspto-grants-2008_11
특허 번호
US07452943B2

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