5-Cyclododecylidenepentanoic acid → 5-Cyclododecylpentanoic acid
반응식
[C:1]1(=[CH:13][CH2:14][CH2:15][CH2:16][C:17]([OH:19])=[O:18])[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1>C(O)(=O)C.[Pt]=O>[CH:1]1([CH2:13][CH2:14][CH2:15][CH2:16][C:17]([OH:19])=[O:18])[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1참가 물질
4
실험 절차
From Example 9Ci above, 0.276 g (0.001 mole) of 5-cyclododecylidene pentanoic acid was dissolved in 30 ml of glacial acetic acid. Platinum oxide (0.027 g) was added and the mixture was hydrogenated on a sloping-manifold hydrogenation apparatus for 3 hr at room temperature. The resultant mixture was then filtered through Celite (diatomaceous earth). The solvent was removed in vacuo to yield 0.26 g (93.8%) of 5-cyclododecylpentanoic acid having the following physical characteristics: