1-Methyl-7-benzoylindoline → 1-Methyl-7-benzoylindole
반응식
[CH3:1][N:2]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][C:9]=2[C:11](=[O:18])[C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH2:4][CH2:3]1>C(Cl)Cl.[O-2].[O-2].[Mn+4]>[CH3:1][N:2]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][C:9]=2[C:11](=[O:18])[C:12]2[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=2)[CH:4]=[CH:3]1참가 물질
4
실험 절차
A mixture of 2.4 grams (0.01 mole) of 1-methyl-7-benzoylindoline and 8.7 grams (0.1 mol) of manganese dioxide in 25 ml of methylene chloride was heated at reflux for 18 hours. The mixture was cooled and filtered. The filtrate was concentrated and the resulting residue was distilled to give 2 grams of 1-methyl-7-benzoylindole having a b.p. of 128° C./0.03 mm Hg.
후처리
- temperaturewas heated
- temperatureat reflux for 18 hours
- temperatureThe mixture was cooled
- filtrationfiltered
- concentrationThe filtrate was concentrated
- distillationthe resulting residue was distilled
출처 및 근거
- ORD 기록
- ord-90919a21f3e44b4aa4b27f128eb16600
- 출처 데이터셋
- uspto-grants-1980_09
- 특허 번호
- US04221716
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