Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzyl Chloride → Benzyl Phenyl Ether
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzyl Chloride | HCID 7503 | — |
| 반응물 | Sodium Phenoxide Trihydrate | HCID 23681143 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | Benzyl Phenyl Ether | HCID 70352 | 67% |
반응 단계
A mixture of sodium phenolate trihydrate (10.2 g; 60 mmole) and benzyl chloride (6.4 ml; 56 mmole) in methanol (150 ml) was pumped through the system (15 ml/minute; 146°-7° C.; 1000-1050 kPa). The MeOH was rotary evaporated off and the residue recrystallised from EtOH to afford colourless needles of phenyl benzyl ether (6.9 g; 67% yield), m.p. 36°-36.3° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05387397 |
| 출처 데이터셋 | uspto-grants-1995_02 |
| ORD ID | ord-80ea20519fd44352987956fe78cc4b12 |
| 출처 메모 | uspto-grants-1995_02 |