1-Aminoanthraquinone → 9,10-Dihydro-9,10-dioxo-1-anthracenesulfonic acid

HRID 273909

반응식

HRID 273909 반응식
N[C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[CH:5]=[CH:4][CH:3]=1.C1C2C(=O)C3C(=CC=CC=3)C(=O)C=2C=CC=1.[OH:34][S:35](O)(=[O:37])=[O:36].O=S(=O)=O>S([O-])([O-])(=O)=O.[Hg+2]>[C:2]1([S:35]([OH:37])(=[O:36])=[O:34])[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[CH:5]=[CH:4][CH:3]=1

참가 물질

5

반응물 3

HCID 67101-AminoanthraquinoneHCID 6780AnthraquinoneHCID 24681Fuming sulfuric acid

생성물 1

HCID 67139,10-Dihydro-9,10-dioxo-1-anthracenesulfonic acid

시약·촉매·용매 1

HCID 24544Mercuric sulfate촉매

실험 절차

GB-A-1 370 413 discloses a two-step synthesis of 1-aminoanthraquinone, in which anthraquinone is sulfonated with oleum in the presence of mercury sulfate to give anthraquinone-1-sulfonic acid and this is reacted in a second step with ammonia to give 1-aminoanthraquinone.

출처 및 근거

ORD 기록
ord-3c8de4837a6d4b68abfd633751347a1e
출처 데이터셋
uspto-grants-1995_02
특허 번호
US05387704

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