참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Eugenol | HCID 3314 | — |
| 반응물 | Methyleugenol | HCID 7127 | — |
| 반응물 | Dimethyl Carbonate | HCID 12021 | — |
| 반응물 | 1,8-Diazabicyclo(5.4.0)undec-7-ene | HCID 81184 | — |
| 생성물 | Methyl isoeugenol | HCID 7128 | 86% |
반응 단계
15 mol of eugenol was charged into a pressure reactor, along with 0.2 mol of 1,8-diazabicyclo[5.4.0]-7-undecene and 16 mol of dimethyl carbonate. The reactor was sealed and was heated to 150° C. After 2 hr, complete conversion of the eugenol was shown to have occurred. After the distillation, 13 mol of eugenol methyl ether and 1 mol of isoeugenol methyl ether were obtained, corresponding to a yield of 86%, based on the starting amount of eugenol.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05387718 |
|---|
| 출처 데이터셋 | uspto-grants-1995_02 |
|---|
| ORD ID | ord-aa17ab4a3614490ebb6e7a894b392bf6 |
|---|
| 출처 메모 | uspto-grants-1995_02 |
|---|
