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Water → HCID 178442091, 화합물

HRID 274163
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인쇄 미리보기

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HRID 274163 반응식
CC(C[AlH]CC(C)C)C.[C:10]([C@H:12]1[CH2:17][CH2:16][C@H:15]([C:18]2[CH:23]=[CH:22][C:21]([C:24]3[CH:29]=[CH:28][C:27]([CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])=[CH:26][CH:25]=3)=[CH:20][CH:19]=2)[CH2:14][CH2:13]1)#N.O.S(=O)(=O)(O)[OH:37]>CCCCCC.CCCCC>[CH:10]([C@H:12]1[CH2:17][CH2:16][C@H:15]([C:18]2[CH:23]=[CH:22][C:21]([C:24]3[CH:29]=[CH:28][C:27]([CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])=[CH:26][CH:25]=3)=[CH:20][CH:19]=2)[CH2:14][CH2:13]1)=[O:37]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

7

반응물 4

HCID 962WaterHCID 1118Sulfuric AcidHCID 14487Diisobutylaluminum hydrideHCID 178442090HCID 178442090, 화합물

생성물 1

HCID 178442091HCID 178442091, 화합물

시약·촉매·용매 2

HCID 8003Pentane용매
HCID 8058
Hexane
용매

실험 절차

112 ml of a 20% solution of DIBALH in hexane are added dropwise to a solution of 33.2 g of 4-(trans-4-cyanocyclohexyl)-4'-pentylbiphenyl in 1 l of pentane, and the mixture is stirred for 18 hours. Water is then added dropwise until the evolution of gas subsides and then 200 ml of 25% sulfuric acid are added dropwise. The organic phase is separated off, dried over Na2SO4 and evaporated. Colourless deliquescent crystals are obtained.

후처리

  1. customThe organic phase is separated off
  2. dry with materialdried over Na2SO4
  3. customevaporated
  4. customColourless deliquescent crystals are obtained

출처 및 근거

ORD 기록
ord-eb5dc1724d7848e3850b97b42f2dc97f
출처 데이터셋
uspto-grants-1995_02
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US05389292

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